James Franco

Where You Can Catch Him: Pineapple Express.

Where You Know Him From: The Spider-Man trilogy, Tristan & Isolde.

Steamy Stats: He's got movie star good looks and an attractive air of mystery about him (see his breakthrough role as James Dean in the 2001 TV biopic). But he's also got a killer sense of humor! Did anyone catch him in the Funnyordie.com Hills spoof where he played Justin Bobby? Hilarious.

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